DEGRADASI PEWARNA TARTRAZIN DENGAN FOTOKATALIS TITANIUM DIOKSIDA (TiO2)
Keywords:
Degradasi, Pewarna Tartrazin, Fotokatalis, Titanium DioksidaAbstract
Tartrazin merupakan jenis pewarna sintetik yang banyak digunakan dalam industri makanan, kosmetik, dan obat-obatan yang apabila jatuh pada badan air dapat mencemarinya sehingga diperlukan senyawa yang dapat mendegradasinya salah satunya dengan menggunakan titanium dioksida (TiO2). Selanjutnya dalam mempelajari mekanisme reaksi dan perubahan yang terjadi selama proses degradasi fotokatalis titanium dioksida diperlukan informasi mengenai tetapan laju, waktu paruh dan laju degradasi yang merupakan faktor penentu dalam mempelajari mekanisme reaksi degradasi tersebut. Penelitian ini bertujuan untuk menentukan massa optimum TiO2 pada saat mendegradasi pewarna Tartrazin, menentukan tetapan laju degradasi tartrazin, menentukan waktu paru degradasi Tartrazin, dan menentukan laju degradasi tartrazin. Adapun prosedur penelitiannya yaitu desain reaktor fotokatalitik, penentuan panjang gelombang maksimum, pembuatan kurva kalibrasi tartrazin, penentuan massa optimum TiO2 dalam mendegradasi senyawa tartrazin, dan penentuan hasil degradasi senyawa tartrazin dengan penyinaran lampu UV. Hasil penelitian ini memperlihatkan bahwa massa optimum TiO2 dalam mendegradasi senyawa tartrazin adalah 50 mg, tetapan laju degradasi adalah 0,006 menit-1, waktu paruh degradasi adalah 115,5 menit dan laju degradasinya mengikuti persamaan reaksi orde pertama dimana laju maksimal terjadi pada menit ke-90 dengan nilai 0,0651 mg/L.
Downloads
Download data is not yet available.
References
[1] N. V. Andari and S. Wardhani, "Fotokatalis TiO2-zeolit untuk degradasi metilen biru," Chemistry Progress, vol. 7, no.1, 2014.
[2] H. Aliah, A. Setiawan, and M. Abdullah, "Pengaruh jumlah lapisan bulir polimer polipropilena berfotokatalis semikonduktor tio2 terhadap fotodegradasi metilen biru," Prosiding SEMIRATA 2013 FMIP, vol. 1. pp. 479-483, 2013.
[3] P.W. Atkins, "Kimia Fisika Edisi Keempat Jilid Dua," Erlangga, Jakarta, 1999.
[4] B. G. Bhernama, "Analisis zat warna tartrazin pada jajanan minuman ringan tak berlabel yang dijual pedagang kaki lima di Banda Aceh," Jurnal Riset Kimia, vol. 9, no. 2, 2016.
[5] I. Fatimah, T. Alawiyah, and I. Sumarlan, "Preparasi fe3+/tio2-montmorillonit sebagai katalis pada degradasi zat warna azo," Reaktor, vol. 14, pp. 255-260, doi: 201310.14710/reaktor.14.4.255-260, 2014.
[6] V. Jaiswal, K. Kalkhanday, S. Umrao, R. B. Rastogi, R. Kumar, and A. Scrivastava, "Synthesis, characterization, and tribological evaluationof TiO2-reinforced boron and nitrogen co-doped reduced grapheneoxide basedhybrid nanomaterials as efficient antiwear lubricant additives," ACS Applied Materials & Interfaces, vol. 8, no. 18, DOI:10.1021/acsami.6b01876, 2016.
[7] S. F. Jayadi, L. Destiarti, and B. Sitorus, "Pembuatan reaktor fotokatalis dan aplikasinya untuk degradasi bahan organik air gambut menggunakan katalis TiO2," Jurnal Kimia Khatulistiwa, vol. 3, no. 3, pp. 55-58, 2014.
[8] S. M. Khopkar, "Konsep Dasar Kimia Analitik," UI-Press. Jakarta. 2003.
[9] Linsebigler, "Photocatalysis on tio2 surfaces: principles, mechanisms, and selected results," Chem. Rev, vol. 95, pp. 735-758, 1995.
[10] E. Marlina, , S. B. A. Hamid, J. C. Juan, W. J. Basirun, and G. Centi, "Synergetic effects in novel hydrogenated F-doped TiO2 photocatalysts," Applied Surface Science, vol. 370., DOI: (201610.1016/j.apsusc.2016.02.172, 2003.
[11] A. Mishra, A. Mehta, and S. Basu, "Clay supported TiO2 nanoparticles for photocatalytic degradation of environmental pollutants: A Review," Journal of Environmental Chemical Engineering, vol. 6, no. 5, DOI:10.1016/j.jece.2018.09.029, 2018.
[12] W. Oliveira, A. Morais, L. Honorio, P. Trigueiro, L. Almeida, R. Garcia, B. Viana, M. Furtini, E. Silva-Filho, and J. Osajima, "TiO2 immobilized on fibrous clay as strategies to photocatalytic activity," Materials Research, vol. 23. DOI: 10.1590/1980-5373-mr-2019-0463, 2020.
[13] L. Retnaningsih, L. Muliani, and G. Wiranto, "Sifat optik campuran pasta tio2 partikel nano dan pasta TiO2 reflektor pada foto elektroda dye solar cell," Jurnal Elektronika dan Telekomunikasi, vol. 14, DOI: 36. 10.14203/jet.v14.36-39, 2016.
[14] J. Rizkiana, A. F. Suyadi, D. Auliardi, H. Devianto, T. H. Soerawidjaja, "Karakterisasi fotokatalis untuk fotoreduksi karbon dioksida menjadi asam format dalam fasa akuatik," Indonesian Journal of Chemical Research, vol. 8, no. 1, pp. 35-42, 2020.
[15] T. Rohman, A. Irwan, and Z. Rahmi, "Penurunan kadar amoniak dan fosfat limbah cair tahu secara foto katalitik menggunakan TiO2 dan H2O2," Jurnal Sains Natural, vol. 8, no. 2, DOI:10.31938/jsn.v8i2.156, 2018.
[16] M. I. Sari, and T. E. Agustina, "Pengaruh penambahan TiO2-powder terhadap kandungan COD pada limbah sintetis C.I. Reacctive Red 2 dengan metode fotokatalisis," Jurnal Teknik Patra Akademika, vol. 10, no. 01, 2019.
[17] M. Sianita, C. Azmiayawati, and A. Darmawan, "Uji fotokatalis genteng berglasir silika /TiO2 terhadap degradasi larutan Indigo Carmine, Metanil Yellow dan Rhodamin," Jurnal Kimia Sains dan Aplikasi, vol. 20, no. 2, DOI:10.14710/jksa.20.2.53-57, 2017.
[18] H. Surahman, "Studi Pengembangan Reaktor Fotokatalitik dengan TiO2 yang Diimobilisasikan pada Dinding Bagian Dalam Kolom Gelas: Optimasi Reaktor Alir dan Uji Kemampuannya Terhadap Degradasi 4-klorofenol" Tesis Magister Ilmu Kimia. Program Pasca Sarjana FMIPA UI. Depok. 2004.
[19] A. S. Suryandari, A. Mustain, D. W. Pratama, and I.Maula, "Studi aktivitas reaksi fotokatalisis berbasis katalis TiO2-karbon aktif terhadap mutu air limbah power plant," Jurnal Teknik Kimia dan Lingkungan, vol. 3, no. 2, 2019.
[20] C. Syahroni, "Degradasi Fotokatalitik Senyawa fenolik dalam Limbah Cair Pabrik kayu lapis dengan Senyawa Fenolik sebagai Model," Tesis Magister Ilmu Kimia, Program Studi magister Ilmu Kimia Program Pasca Sarjana FMIPA UI. Depok. 2006.
[21] S. Titdoy, A. D. Wuntu, and V. S. Kamu, "Kinetika fotodegradasi remazol yellow menggunakan zeolit A terinpregrnasi TiO2," Jurnal MIPA UNSRAT, vol. 5, no. 1, pp. 10-13, 2016.
[22] R.T. Tjahjanto, and J. Gunlazuardi, "Preparasi Lapisan Tipis TiO2 sebagai Fotokatalis : Keterkaitan antara Ketebalan dan Aktivitas Fotokatalisis," Penelitian Universitas Indonesia, vol 5, no 2, 81-91. Jakarta. 2001
[23] K. Vignesh, S. Mathew, J. Bartlett, and S. Pillai, "Photocatalytic hydrogen production using metal doped TiO2: A review of recent advances," Applied Catalysis B: Environmental, 244. 2018.
[24] F.G. Winarno, "Kimia Pangan dan Gizi," Gramedia Pustaka Utama. Jakarta. 1997.
[25] B. Zhang, X. He, X.Ma, Q. Chen, G. Liu, Y. Zhou, D. Ma, C. Cui, J. Ma, and Y. Xin, "In situ synthesis of ultrafine TiO2 nanoparticles modified g-C3N4 heterojunction photocatalyst with enhanced photocatalytic activity," Separation and Purification Technology, 247. 2020.
[26] J. Zhang, P. Zhou, J. Liu, and J. Yu, "New Understanding of the difference of photocatalytic activity among anatase, rutile, and brookite TiO2," Phys. Chem, vol. 16, 2014.
[2] H. Aliah, A. Setiawan, and M. Abdullah, "Pengaruh jumlah lapisan bulir polimer polipropilena berfotokatalis semikonduktor tio2 terhadap fotodegradasi metilen biru," Prosiding SEMIRATA 2013 FMIP, vol. 1. pp. 479-483, 2013.
[3] P.W. Atkins, "Kimia Fisika Edisi Keempat Jilid Dua," Erlangga, Jakarta, 1999.
[4] B. G. Bhernama, "Analisis zat warna tartrazin pada jajanan minuman ringan tak berlabel yang dijual pedagang kaki lima di Banda Aceh," Jurnal Riset Kimia, vol. 9, no. 2, 2016.
[5] I. Fatimah, T. Alawiyah, and I. Sumarlan, "Preparasi fe3+/tio2-montmorillonit sebagai katalis pada degradasi zat warna azo," Reaktor, vol. 14, pp. 255-260, doi: 201310.14710/reaktor.14.4.255-260, 2014.
[6] V. Jaiswal, K. Kalkhanday, S. Umrao, R. B. Rastogi, R. Kumar, and A. Scrivastava, "Synthesis, characterization, and tribological evaluationof TiO2-reinforced boron and nitrogen co-doped reduced grapheneoxide basedhybrid nanomaterials as efficient antiwear lubricant additives," ACS Applied Materials & Interfaces, vol. 8, no. 18, DOI:10.1021/acsami.6b01876, 2016.
[7] S. F. Jayadi, L. Destiarti, and B. Sitorus, "Pembuatan reaktor fotokatalis dan aplikasinya untuk degradasi bahan organik air gambut menggunakan katalis TiO2," Jurnal Kimia Khatulistiwa, vol. 3, no. 3, pp. 55-58, 2014.
[8] S. M. Khopkar, "Konsep Dasar Kimia Analitik," UI-Press. Jakarta. 2003.
[9] Linsebigler, "Photocatalysis on tio2 surfaces: principles, mechanisms, and selected results," Chem. Rev, vol. 95, pp. 735-758, 1995.
[10] E. Marlina, , S. B. A. Hamid, J. C. Juan, W. J. Basirun, and G. Centi, "Synergetic effects in novel hydrogenated F-doped TiO2 photocatalysts," Applied Surface Science, vol. 370., DOI: (201610.1016/j.apsusc.2016.02.172, 2003.
[11] A. Mishra, A. Mehta, and S. Basu, "Clay supported TiO2 nanoparticles for photocatalytic degradation of environmental pollutants: A Review," Journal of Environmental Chemical Engineering, vol. 6, no. 5, DOI:10.1016/j.jece.2018.09.029, 2018.
[12] W. Oliveira, A. Morais, L. Honorio, P. Trigueiro, L. Almeida, R. Garcia, B. Viana, M. Furtini, E. Silva-Filho, and J. Osajima, "TiO2 immobilized on fibrous clay as strategies to photocatalytic activity," Materials Research, vol. 23. DOI: 10.1590/1980-5373-mr-2019-0463, 2020.
[13] L. Retnaningsih, L. Muliani, and G. Wiranto, "Sifat optik campuran pasta tio2 partikel nano dan pasta TiO2 reflektor pada foto elektroda dye solar cell," Jurnal Elektronika dan Telekomunikasi, vol. 14, DOI: 36. 10.14203/jet.v14.36-39, 2016.
[14] J. Rizkiana, A. F. Suyadi, D. Auliardi, H. Devianto, T. H. Soerawidjaja, "Karakterisasi fotokatalis untuk fotoreduksi karbon dioksida menjadi asam format dalam fasa akuatik," Indonesian Journal of Chemical Research, vol. 8, no. 1, pp. 35-42, 2020.
[15] T. Rohman, A. Irwan, and Z. Rahmi, "Penurunan kadar amoniak dan fosfat limbah cair tahu secara foto katalitik menggunakan TiO2 dan H2O2," Jurnal Sains Natural, vol. 8, no. 2, DOI:10.31938/jsn.v8i2.156, 2018.
[16] M. I. Sari, and T. E. Agustina, "Pengaruh penambahan TiO2-powder terhadap kandungan COD pada limbah sintetis C.I. Reacctive Red 2 dengan metode fotokatalisis," Jurnal Teknik Patra Akademika, vol. 10, no. 01, 2019.
[17] M. Sianita, C. Azmiayawati, and A. Darmawan, "Uji fotokatalis genteng berglasir silika /TiO2 terhadap degradasi larutan Indigo Carmine, Metanil Yellow dan Rhodamin," Jurnal Kimia Sains dan Aplikasi, vol. 20, no. 2, DOI:10.14710/jksa.20.2.53-57, 2017.
[18] H. Surahman, "Studi Pengembangan Reaktor Fotokatalitik dengan TiO2 yang Diimobilisasikan pada Dinding Bagian Dalam Kolom Gelas: Optimasi Reaktor Alir dan Uji Kemampuannya Terhadap Degradasi 4-klorofenol" Tesis Magister Ilmu Kimia. Program Pasca Sarjana FMIPA UI. Depok. 2004.
[19] A. S. Suryandari, A. Mustain, D. W. Pratama, and I.Maula, "Studi aktivitas reaksi fotokatalisis berbasis katalis TiO2-karbon aktif terhadap mutu air limbah power plant," Jurnal Teknik Kimia dan Lingkungan, vol. 3, no. 2, 2019.
[20] C. Syahroni, "Degradasi Fotokatalitik Senyawa fenolik dalam Limbah Cair Pabrik kayu lapis dengan Senyawa Fenolik sebagai Model," Tesis Magister Ilmu Kimia, Program Studi magister Ilmu Kimia Program Pasca Sarjana FMIPA UI. Depok. 2006.
[21] S. Titdoy, A. D. Wuntu, and V. S. Kamu, "Kinetika fotodegradasi remazol yellow menggunakan zeolit A terinpregrnasi TiO2," Jurnal MIPA UNSRAT, vol. 5, no. 1, pp. 10-13, 2016.
[22] R.T. Tjahjanto, and J. Gunlazuardi, "Preparasi Lapisan Tipis TiO2 sebagai Fotokatalis : Keterkaitan antara Ketebalan dan Aktivitas Fotokatalisis," Penelitian Universitas Indonesia, vol 5, no 2, 81-91. Jakarta. 2001
[23] K. Vignesh, S. Mathew, J. Bartlett, and S. Pillai, "Photocatalytic hydrogen production using metal doped TiO2: A review of recent advances," Applied Catalysis B: Environmental, 244. 2018.
[24] F.G. Winarno, "Kimia Pangan dan Gizi," Gramedia Pustaka Utama. Jakarta. 1997.
[25] B. Zhang, X. He, X.Ma, Q. Chen, G. Liu, Y. Zhou, D. Ma, C. Cui, J. Ma, and Y. Xin, "In situ synthesis of ultrafine TiO2 nanoparticles modified g-C3N4 heterojunction photocatalyst with enhanced photocatalytic activity," Separation and Purification Technology, 247. 2020.
[26] J. Zhang, P. Zhou, J. Liu, and J. Yu, "New Understanding of the difference of photocatalytic activity among anatase, rutile, and brookite TiO2," Phys. Chem, vol. 16, 2014.
Downloads
Published
2021-10-28
How to Cite
[1]
A. Said, “DEGRADASI PEWARNA TARTRAZIN DENGAN FOTOKATALIS TITANIUM DIOKSIDA (TiO2)”, CJCS, vol. 3, no. 1, pp. 21–27, Oct. 2021.
Issue
Section
Articles
License
In submitting the manuscript to the journal, the authors certify that:
- They are authorized by their co-authors to enter into these arrangements.
- The work described has not been formally published before, except in the form of an abstract or as part of a published lecture, review, thesis, or overlay journal.
- That it is not under consideration for publication elsewhere,
- That its publication has been approved by all the author(s) and by the responsible authorities – tacitly or explicitly – of the institutes where the work has been carried out.
- They secure the right to reproduce any material that has already been published or copyrighted elsewhere.
- They agree to the following license and copyright agreement.
License and Copyright Agreement
Authors who publish with this journal agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under Creative Commons Attribution License (CC BY 4.0) that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this journal.
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work.
